Complex thermal expansion properties in a molecular honeycomb lattice.

نویسندگان

  • Jonathan J Loughrey
  • Tim P Comyn
  • David C Apperley
  • Marc A Little
  • Malcolm A Halcrow
چکیده

[FeL3][BF4]2·xH2O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150-240 K but positive thermal expansion at 240-300 K, linked to rearrangement of anions and water molecules within pores in the lattice.

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عنوان ژورنال:
  • Chemical communications

دوره 50 57  شماره 

صفحات  -

تاریخ انتشار 2014